HCID 14090569、化合物 → Tetrahydro-M-Xylylene Dicarbamate
反応式
C(=O)(OCC(F)(F)C(F)(F)C(F)(F)C(F)F)OCC(F)(F)C(F)(F)C(F)(F)C(F)F.FC(F)(C(F)(F)C(F)(F)C(F)F)C[NH:34][C:35](=[O:62])[O:36][CH2:37][CH:38]1[CH:43]=[CH:42][CH2:41][CH:40]([CH2:44][O:45][C:46](=[O:61])[NH:47]CC(F)(F)C(F)(F)C(F)(F)C(F)F)[CH2:39]1>>[C:46](=[O:61])([O:45][CH2:44][CH:40]1[CH:41]=[CH:42][CH2:43][CH:38]([CH2:37][O:36][C:35](=[O:62])[NH2:34])[CH2:39]1)[NH2:47]参加物
3
実験手順
The reaction was carried out in the same manner as Example 7 except for using 80.5 g (0.1642 mol) of bis(2,2,3,3,4,4,5,5-octafluoropentyl) carbonate (to be referred to as “BOFC” hereinafter) synthesized in the above Synthesis Example 4 in place of BTFC, and it Was confirmed that tetrahydro-m-xylylene bis(2,2,3,3,4,4,5,5-octafluoropentyl carbamate) (to be referred to as H-XDC-4 hereinafter) was generated as the main product (H-XDA base yield 98.0%). Structural assignment of the product H-XDC-4 was carried out by 19F-NMR and GC-Mass analyses as well as 1H-NMR. Analytical Results of mass fragments of H-XDC-4, 1H-NMR and 19F-NMR were shown in the following.
後処理
- customsynthesized in the above Synthesis Example 4 in place of BTFC, and it
- customAnalytical Results of mass fragments of H-XDC-4, 1H-NMR and 19F-NMR
出典と根拠
- ORDレコード
- ord-b09773a5c2da4709b53a58c62423cce5
- 出典データセット
- uspto-grants-2016_02
- 特許番号
- US09260383B2
反応ノート
読み込み中…