Stearyl Alcohol → 1-Dodecanol

HRID 17749

反応式

HRID 17749 の反応式
C(NCCCCCCCCCCCCCCCCCC)CCCCCCCCCCCCCCCCC.[C:38]([O:61][CH2:62][CH2:63][OH:64])(=[O:60])[CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH2:44][CH2:45][CH2:46][CH2:47][CH2:48][CH2:49]CCCCCCCCCC.[C:65](OC[C:86]([CH2:91][OH:92])([CH2:89][OH:90])CO)(=[O:83])[CH2:66][CH2:67][CH2:68][CH2:69][CH2:70][CH2:71][CH2:72]/[CH:73]=[CH:74]\[CH2:75][CH2:76][CH2:77][CH2:78][CH2:79][CH2:80][CH2:81][CH3:82].[CH2:93]([OH:111])CCCCCCCCCCCCCCCCC.C(O)(=[O:130])CCCCCCC/C=C\CCCCCCCC>>[CH2:38]([OH:60])[CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH2:44][CH2:45][CH2:46][CH2:47][CH2:48][CH3:49].[CH2:65]([OH:83])[CH2:66][CH2:67][CH2:68][CH2:69][CH2:70][CH2:71][CH2:72][CH2:73][CH2:74][CH2:75][CH2:76][CH2:77][CH2:78][CH2:79][CH2:80][CH2:81][CH3:82].[CH:44]1[CH:43]=[CH:42][C:41](/[CH:40]=[CH:39]/[CH2:38][O:61][C@@H:62]2[O:130][C@H:86]([CH2:89][OH:90])[C@@H:91]([OH:92])[C@H:93]([OH:111])[C@H:63]2[OH:64])=[CH:46][CH:45]=1

参加物

8

反応物 5

HCID 8221Stearyl AlcoholHCID 66989DioctadecylamineHCID 445639Oleic AcidHCID 6436366Pentaerythritol monooleateHCID 187695902-Hydroxyethyl docosanoate

生成物 3

HCID 81931-DodecanolHCID 8221Stearyl AlcoholHCID 5280656(2R,3S,4S,5R,6R)-2-(hydroxymethyl)-6-[(E)-3-phenylprop-2-enoxy]oxane-3,4,5-triol

実験手順

Details of the (A), (B) and (C) components in Table 1, Table 1-2, Table 2, and Table-3 are as follows: (A) Component A-1: Pentaerythritol stearate (average ester replacement degree 45% by equivalent), A-2: Long chain fatty acid polyamide polyamine (MW=3,000 to 4,000); obtained by dropwise adding epichlorohydrin (1/3 mole ratio) to a compound obtained by reaction of polyethylene imine (MW=1,000) and Lunac S-40 (1/7 mole ratio) manufactured by Kao Corporation, A-3: Distearylamine, A-4: Ethylene glycol monobehenate, A-5: Pentaerythritol monooleate (average ester replacement degree 45% by equivalent), A-6: Stearyl alcohol PO adduct (PO=10 mole), A-7: Oleic acid, A-8: Beef tallow, A-9: Cured castor oil, A-10: Lauryl alcohol EO Adduct (EO=15 mole), A-11: Stearyl alcohol EO/PO adduct (EO 24/PO 18 random adduct), A-12: KB-115 (manufactured by Kao Corporation) (main component: fatty acid polyhydric alcohol ester), A-13: Rosin (Hartall R-WW, manufactured by Harima Chemicals, Inc.), A-14: Alkyl ketene dimer obtained by de-hydrochloric acid reaction, in the presence of ternary amine catalyst, of fatty acid chloride obtained by the reaction of phosphoric acid trichloride with Lunac S-40 (manufactured by Kao Corporation), A-15: Alkenyl succinic acid anhydride obtained by addition reaction of Dialen 168 manufactured by Mitsubishi Chemical Industries Ltd. and maleic anhydride at 3/2 mole ratio, and A-16: Methylpolysiloxane (KF96A-1000, manufactured by Shin-Etsu Silicone Co., Ltd.).

出典と根拠

ORDレコード
ord-a14edf286595459bbce8fa7caecbf265
出典データセット
uspto-grants-2010_06
特許番号
US07740742B2

関連ノート

読み込み中…