Triethylamine → 3-Nitrooxy-propyl hexanoate
反応式
[N+:1]([O:4][CH2:5][CH2:6][CH2:7][OH:8])([O-:3])=[O:2].C(N(CC)CC)C.[C:16](Cl)(=[O:22])[CH2:17][CH2:18][CH2:19][CH2:20][CH3:21]>C(OCC)C>[C:16]([O:8][CH2:7][CH2:6][CH2:5][O:4][N+:1]([O-:3])=[O:2])(=[O:22])[CH2:17][CH2:18][CH2:19][CH2:20][CH3:21]参加物
5
実験手順
20 mmol 3-Nitrooxypropanol dissolved in 10 ml Diethylether and 20 mmol Triethylamine were cooled to 0° C. 18.2 mmol hexoylchlorid were dropped over a period of 5 minutes at 0 to 5° C. After 19 hours stirring without cooling, the reaction mixture was extracted with 1N HCl, twice with water, washed with brine, dried over Na2SO4 and the solvent was removed in vacuo leaving 3.1 g.
後処理
- temperaturewithout cooling
- extractionthe reaction mixture was extracted with 1N HCl, twice with water
- washwashed with brine
- dry with materialdried over Na2SO4
- customthe solvent was removed in vacuo
- customleaving 3.1 g
出典と根拠
- ORDレコード
- ord-c4a2063d7aa746b795570185b067c6fa
- 出典データセット
- uspto-grants-2016_02
- 特許番号
- US09266814B2
反応ノート
読み込み中…