Benzenamine, N,N-dimethyl-, hydrochloride (1:1) → N,N-dimethylanilinium tetrakis(pentafluorophenyl)borate

HRID 1780044

反応式

HRID 1780044 の反応式
[F:1][C:2]1[C:7]([B-:8]([C:31]2[C:36]([F:37])=[C:35]([F:38])[C:34]([F:39])=[C:33]([F:40])[C:32]=2[F:41])([C:20]2[C:25]([F:26])=[C:24]([F:27])[C:23]([F:28])=[C:22]([F:29])[C:21]=2[F:30])[C:9]2[C:14]([F:15])=[C:13]([F:16])[C:12]([F:17])=[C:11]([F:18])[C:10]=2[F:19])=[C:6]([F:42])[C:5]([F:43])=[C:4]([F:44])[C:3]=1[F:45].[Li+].Cl.[CH3:48][N:49]([CH3:56])[C:50]1[CH:55]=[CH:54][CH:53]=[CH:52][CH:51]=1>O>[F:37][C:36]1[C:31]([B-:8]([C:9]2[C:14]([F:15])=[C:13]([F:16])[C:12]([F:17])=[C:11]([F:18])[C:10]=2[F:19])([C:7]2[C:6]([F:42])=[C:5]([F:43])[C:4]([F:44])=[C:3]([F:45])[C:2]=2[F:1])[C:20]2[C:21]([F:30])=[C:22]([F:29])[C:23]([F:28])=[C:24]([F:27])[C:25]=2[F:26])=[C:32]([F:41])[C:33]([F:40])=[C:34]([F:39])[C:35]=1[F:38].[CH3:48][NH+:49]([CH3:56])[C:50]1[CH:55]=[CH:54][CH:53]=[CH:52][CH:51]=1

参加物

4

反応物 2

HCID 79987Benzenamine, N,N-dimethyl-, hydrochloride (1:1)HCID 23709652Lithium tetrakis(pentafluorophenyl)borate

生成物 1

HCID 10996402N,N-dimethylanilinium tetrakis(pentafluorophenyl)borate収率 71.3%

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

Thereafter, lithium tetrakis(pentafluorophenyl)borate (16 mmol) was reacted with dimethylaniline hydrochloride (16 mmol) in water, to obtain 11.4 mmol of dimethylanilinium tetrakis(pentafluorophenyl)borate as a white solid product.

出典と根拠

ORDレコード
ord-ad9997bd2aca46629b0e752b6e376079
出典データセット
uspto-grants-1997_05
特許番号
US05629398

関連ノート

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