Ethyl 4-methylidenecyclohexane-1-carboxylate → 4-Methylenecyclohexylmethanol
反応式
C([O:3][C:4]([CH:6]1[CH2:11][CH2:10][C:9](=[CH2:12])[CH2:8][CH2:7]1)=O)C.[H-].[H-].[H-].[H-].[Li+].[Al+3]>>[CH2:12]=[C:9]1[CH2:10][CH2:11][CH:6]([CH2:4][OH:3])[CH2:7][CH2:8]1参加物
3
実験手順
The reduction reaction of 4-methylene-cyclohexanecarboxylic acid ethyl ester with LAH is as described in the above reference. The product was purified by distillation to provide (4-methylene-cyclohexyl)-methanol as clear oil (3.67 g, 29.09 mmol, 50% over Step A and B).
後処理
- distillationThe product was purified by distillation
出典と根拠
- ORDレコード
- ord-bd9245b2f7094d11a58f50b566c68df3
- 出典データセット
- uspto-grants-2009_03
- 特許番号
- US07501408B2
反応ノート
読み込み中…