Vinyl Acetate → Triethylene glycol monovinyl ether monoacetate

HRID 1792251

反応式

HRID 1792251 の反応式
[C:1]([O-:4])(=[O:3])[CH3:2].[Na+].C(O)COCCOCCO.C(OC=C)(=O)C.[CH:22]([O:24][CH2:25][CH2:26][O:27][CH2:28][CH2:29][O:30][CH2:31][CH2:32]OC=C)=[CH2:23].C(OCCOCCOCCO)=C>C1(C)C=CC=CC=1>[C:1]([O:4][CH2:32][CH2:31][O:30][CH2:29][CH2:28][O:27][CH2:26][CH2:25][O:24][CH:22]=[CH2:23])(=[O:3])[CH3:2]

参加物

7

反応物 5

HCID 7904Vinyl AcetateHCID 8172Triethylene GlycolHCID 517045Sodium AcetateHCID 575880Ethanol, 2-(2-(2-(ethenyloxy)ethoxy)ethoxy)-HCID 3033992Triethylene glycol divinyl ether

生成物 1

HCID 22034547Triethylene glycol monovinyl ether monoacetate

試薬・触媒・溶媒 1

HCID 1140Toluene溶媒

反応条件

温度
100 °C

実験手順

To a mixture of di-μ-chlorobis(1,5-cyclooctadiene)diiridium(I) [Ir(cod)Cl]2 (0.01 mmol) and sodium acetate (1.2 mmol) in toluene (2.0 ml),triethylene glycol (1 mmol) and vinyl acetate (4 mmol) were added, followed by stirring at 100° C. in an atmosphere of argon gas for 6 hours. The reaction mixture was analyzed by gas chromatography to find that triethylene glycol divinyl ether, triethylene glycol monovinyl ether, and triethylene glycol monovinyl ether monoacetate were produced in yields of 63%, 3%, and 18%, respectively, with a conversion from triethylene glycol of 100%.

後処理

  1. additionwere added

出典と根拠

ORDレコード
ord-23d6d4ffa44348848a0b664c32a65c64
出典データセット
uspto-grants-2006_07
特許番号
US07074970B2

関連ノート

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