1-Methylindole → Bis(1-methylindol-3-yl)-(1,1'-biphenyl-4-yl)methane

反応式

[CH3:1][N:2]1[C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[CH:4]=[CH:3]1.[C:11]1([C:19]2[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=2)[CH:16]=[CH:15][C:14]([CH:17]=O)=[CH:13][CH:12]=1>>[CH3:1][N:2]1[C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[C:4]([CH:17]([C:4]2[C:5]3[C:10](=[CH:9][CH:8]=[CH:7][CH:6]=3)[N:2]([CH3:1])[CH:3]=2)[C:14]2[CH:15]=[CH:16][C:11]([C:19]3[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=3)=[CH:12][CH:13]=2)=[CH:3]1

参加物

反応物 2

HCID 117811-Methylindole

HCID 76689(1,1'-Biphenyl)-4-carboxaldehyde

生成物 1

HCID 10180866Bis(1-methylindol-3-yl)-(1,1'-biphenyl-4-yl)methane

実験手順

The compound Bis(1-methylindol-3-yl)-(1,1′-biphenyl-4-yl)methane was prepared following procedure A, starting from N-methyl indole and 4-biphenyl carboxaldehyde. LC: Tr 2.92 min, MS: 427 (M+H)+

後処理

customTr 2.92 min, MS

出典と根拠

ORDレコード: ord-e16e3fdf47664e9e950c15191f1b5cb4
出典データセット: uspto-grants-2006_04
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US07022730B2

反応ノート

読み込み中…