Phenylacetylene → Copper (I) phenylacetylide

HRID 1796955ノート

反応式

HRID 1796955 の反応式
[C:1]1([C:7]#[CH:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[Cu:9](I)I>C(O)C.[NH4+].[OH-].O>[C-:8]#[C:7][C:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[Cu+:9]

参加物

6

反応物 2

HCID 10821PhenylacetyleneHCID 83717Copper iodide

生成物 1

HCID 4478696Copper (I) phenylacetylide

試薬・触媒・溶媒 3

HCID 702Ethanol溶媒HCID 962Water溶媒HCID 14923Ammonium Hydroxide溶媒

実験手順

To a solution of 10.7 g of phenylacetylene in 500 ml of absolute ethanol was added a solution of 20 g of copper iodide in 250 ml of conc. NH4OH and 100 ml of water. The solution was stirred 30 minutes and then filtered. The solid that was collected was washed with water, 95% aq. Ethanol and then ether. The solid was then collected and dried under vacuum to provide the title compound as a bright yellow solid.

後処理

  1. filtrationfiltered
  2. customThe solid that was collected
  3. washwas washed with water, 95% aq. Ethanol
  4. customThe solid was then collected
  5. customdried under vacuum

出典と根拠

ORDレコード
ord-bc280e876c9a4d4082b16e500a23e038
出典データセット
uspto-grants-2006_04
特許番号
US07034026B2

反応ノート

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