Potassium Carbonate → Ethyl 4-(benzyloxy)-3-hydroxybenzoate

HRID 1810918ノート

反応式

HRID 1810918 の反応式
[CH2:1]([O:3][C:4](=[O:23])[C:5]1[CH:10]=[CH:9][C:8]([O:11][CH2:12][C:13]2[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=2)=[C:7]([O:19]C(=O)C)[CH:6]=1)[CH3:2].C(=O)([O-])[O-].[K+].[K+]>CO>[CH2:1]([O:3][C:4](=[O:23])[C:5]1[CH:10]=[CH:9][C:8]([O:11][CH2:12][C:13]2[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=2)=[C:7]([OH:19])[CH:6]=1)[CH3:2]

参加物

4

反応物 2

HCID 11430Potassium CarbonateHCID 67170201HCID 67170201、化合物

生成物 1

HCID 11311797Ethyl 4-(benzyloxy)-3-hydroxybenzoate

試薬・触媒・溶媒 1

HCID 887Methanol溶媒

実験手順

The compound of step 1 (10 g, 31.8 mmol) was dissolved in methanol, potassium carbonate (88 mg, 0.636 mmol) was added and the mixture was stirred for 2 h under reflux. After evaporation to dryness, the residue was used without further purification in the subsequent step.

後処理

  1. temperatureunder reflux
  2. customAfter evaporation to dryness
  3. customthe residue was used without further purification in the subsequent step

出典と根拠

ORDレコード
ord-847ccc0412f24323a43d8dcb4df6878b
出典データセット
uspto-grants-2013_01
特許番号
US08362073B2

反応ノート

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