化工社化工社 化学情報印刷レポート · 研究参考用
Methylamine → 6H-oxazolo[4,5-e]indole
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Methylamine | HCID 6329 | — |
| 反応物 | 5-Hydroxyindole | HCID 16054 | — |
| 触媒 | Manganese dioxide | HCID 14801 | — |
| 溶媒 | Dimethylformamide | HCID 6228 | — |
| 生成物 | 6H-oxazolo[4,5-e]indole | HCID 11332609 | — |
反応手順
0.5 mmol of methylamine and 4.13 mmol of MnO2 are added to a solution of 0.4 mmol of 5-hydroxy-1H-indole in 3 ml of DMF, and the mixture is stirred at room temperature for 18 hours. The suspension is filtered through Celite and subjected to conventional work-up, giving 6H-oxazolo[4,5-e]indole; ESI 159.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US07741343B2 |
| 出典データセット | uspto-grants-2010_06 |
| ORD ID | ord-48e2ebd3ce31455ea6dd59c9383f0a06 |
| 出典メモ | uspto-grants-2010_06 |