HCID 22142146、化合物 → HCID 67457713、化合物
反応式
[F:1][C:2]([F:25])([F:24])[C:3]1[CH:4]=[C:5]([CH:21]=[CH:22][CH:23]=1)[O:6][C:7]1[CH:12]=[CH:11][C:10]([NH:13][NH:14][C:15]([O:17][CH:18]([CH3:20])[CH3:19])=[O:16])=[CH:9][CH:8]=1.Cl[O-].[Na+]>ClCCl>[F:1][C:2]([F:24])([F:25])[C:3]1[CH:4]=[C:5]([CH:21]=[CH:22][CH:23]=1)[O:6][C:7]1[CH:12]=[CH:11][C:10]([N:13]=[N:14][C:15]([O:17][CH:18]([CH3:20])[CH3:19])=[O:16])=[CH:9][CH:8]=1参加物
4
実験手順
To the product (0.42 g) of Step 4 of Example 1 was added dichloromethane (10 mL) and 5% aqueous sodium hypochlorite (20 mL). The two-phase mixture was stirred vigorously overnight at room temperature, the organic layer was separated, dried over anhydrous sodium sulfate, and concentrated under reduced pressure to give a red oil (0.4 g).