Hydrogen iodide → HCID 22138046、化合物

HRID 1827605ノート

反応式

HRID 1827605 の反応式
[CH:1]1[C:14]2[CH:13]=[C:12]([C:15]3[CH:16]=[C:17]([C:21]4(O)[C:34]5[CH:33]=[CH:32][CH:31]=[CH:30][C:29]=5[C:28]([C:36]5[CH:41]=[CH:40][CH:39]=[C:38]([C:42]6[C:43]7[C:48]([C:49]8[CH:50]=[CH:51][CH:52]=[CH:53][C:54]=8[CH:55]=6)=[CH:47][CH:46]=[CH:45][CH:44]=7)[CH:37]=5)(O)[C:27]5[C:22]4=[CH:23][CH:24]=[CH:25][CH:26]=5)[CH:18]=[CH:19][CH:20]=3)[C:11]3[C:6](=[CH:7][CH:8]=[CH:9][CH:10]=3)[C:5]=2[CH:4]=[CH:3][CH:2]=1.I.[PH2](O)=O>C(O)(=O)C>[CH:1]1[C:14]2[CH:13]=[C:12]([C:15]3[CH:16]=[C:17]([C:21]4[C:22]5[C:27]([C:28]([C:36]6[CH:41]=[CH:40][CH:39]=[C:38]([C:42]7[C:43]8[C:48]([C:49]9[CH:50]=[CH:51][CH:52]=[CH:53][C:54]=9[CH:55]=7)=[CH:47][CH:46]=[CH:45][CH:44]=8)[CH:37]=6)=[C:29]6[C:34]=4[CH:33]=[CH:32][CH:31]=[CH:30]6)=[CH:26][CH:25]=[CH:24][CH:23]=5)[CH:18]=[CH:19][CH:20]=3)[C:11]3[C:6](=[CH:7][CH:8]=[CH:9][CH:10]=3)[C:5]=2[CH:4]=[CH:3][CH:2]=1

参加物

5

反応物 3

HCID 24841Hydrogen iodideHCID 4124402Phosphinic AcidHCID 22138029HCID 22138029、化合物

生成物 1

HCID 22138046HCID 22138046、化合物

試薬・触媒・溶媒 1

HCID 176Acetic Acid溶媒

反応条件

温度
100 °C

実験手順

9,10-bis(3-(9-Phenanthryl)phenyl)-9,10-dihydroxy-9,10-dihydroanthracene (5.2 g, 7.3 mmole) was suspended in acetic acid (120 ml). To the resultant suspension, a 57% hydroiodic acid (10 ml, 77 mmole, 10 eq) was added and the obtained mixture was stirred at 100° C. for 6 hours. To the reaction mixture, a 50% aqueous solution of hypophosphorous acid (40 ml) was added. The formed solid was separated by filtration and washed with water, methanol and acetone and a white solid (5.0 g, quant.) was obtained.

後処理

  1. customThe formed solid was separated by filtration
  2. washwashed with water, methanol and acetone
  3. customa white solid (5.0 g, quant.) was obtained

出典と根拠

ORDレコード
ord-8ecb8f81b0c04c17b53fe80b7692d8c9
出典データセット
uspto-grants-2006_05
特許番号
US07053255B2

反応ノート

読み込み中…