Water → Tatb

HRID 1828378

反応式

HRID 1828378 の反応式
[NH2:1][C:2]1[C:10]([N+:11]([O-:13])=[O:12])=[C:9](O)[C:5]([N+:6]([O-:8])=[O:7])=[C:4]([NH2:15])[C:3]=1[N+:16]([O-:18])=[O:17].P([O-])([O-])(O)=O.[NH4+:24].[NH4+].O>S1(CCCC1)(=O)=O>[C:9]1([NH2:24])[C:10]([N+:11]([O-:13])=[O:12])=[C:2]([NH2:1])[C:3]([N+:16]([O-:18])=[O:17])=[C:4]([NH2:15])[C:5]=1[N+:6]([O-:8])=[O:7]

参加物

5

反応物 3

HCID 962WaterHCID 24540Diammonium hydrogen phosphateHCID 5249535Phenol, 3,5-diamino-2,4,6-trinitro-

生成物 1

HCID 18286Tatb

試薬・触媒・溶媒 1

HCID 31347Sulfolane溶媒

反応条件

温度
177 °C

実験手順

Diaminopicric acid (0.193 g, 0.748 mmol) and diammonium hydrogen phosphate (0.990 g, 7.50 mmol) are suspended in dry sulfolane (3 ml) and stirred in a Teflon® capped glass pressure tube (8 ml). The suspension is heated with stirring from ambient temperature to 177° C. over a 2 hr period. Stirring and heating (177° C.) is continued for an additional 6 hours. The reaction tube is cooled to 4° C. and the resulting suspension is mixed with water (40 ml). The precipitated product is collected, washed with water and dried to yield TATB in the form of a brown solid (0.154 g, 80%).

後処理

  1. customcapped glass pressure tube (8 ml)
  2. temperatureThe suspension is heated
  3. stirringStirring
  4. waitis continued for an additional 6 hours
  5. temperatureThe reaction tube is cooled to 4° C.
  6. customThe precipitated product is collected
  7. washwashed with water
  8. customdried

出典と根拠

ORDレコード
ord-77a1c98cd36c4f778752be063b9d06cc
出典データセット
uspto-grants-2006_06
特許番号
US07057073B2

関連ノート

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