1-Nitrodecane → 3(S)-Amino-3,5-dimethyl-octanoic Acid

反応式

N[C@@](C)(CC(C)CC)CC(O)=O.[NH2:13][C@@:14]([CH3:26])([CH2:19][CH:20]([CH3:25])[CH2:21][CH2:22][CH2:23]C)[CH2:15][C:16]([OH:18])=[O:17].C([N+]([O-])=O)CCCCCCCCC>>[NH2:13][C@@:14]([CH3:26])([CH2:19][CH:20]([CH3:25])[CH2:21][CH2:22][CH3:23])[CH2:15][C:16]([OH:18])=[O:17]

参加物

反応物 3

HCID 2206471-Nitrodecane

HCID 118165083(S)-Amino-3,5-dimethyl-nonanoic acid

HCID 210313013(S)-Amino-3,5-dimethyl-heptanoic acid

生成物 1

HCID 210313023(S)-Amino-3,5-dimethyl-octanoic Acid

実験手順

A procedure similar to that of 3(S)-Amino-3,5-dimethyl-heptanoic acid was used to prepare 3(S)-Amino-3,5-dimethyl-nonanoic acid. m/z 188.1 (C10H21NO2+H).

出典と根拠

ORDレコード: ord-501eb9515277488690ff994a9e768c25
出典データセット: uspto-grants-2006_06
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US07064147B2

反応ノート

読み込み中…