Hydrochloric Acid → HCID 21388725、化合物
反応式
Cl[C:2]1[CH:10]=[C:9]([CH3:11])[C:8]([N+:12]([O-:14])=[O:13])=[CH:7][C:3]=1[C:4]([NH2:6])=[O:5].C[NH:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH3:30].Cl.[CH2:32](N(CC)CC)C>>[CH3:32][CH:18]([CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH3:30])[CH2:17][NH:16][C:2]1[CH:10]=[C:9]([CH3:11])[C:8]([N+:12]([O-:14])=[O:13])=[CH:7][C:3]=1[C:4]([NH2:6])=[O:5]参加物
5
実験手順
A mixture of 19.2 grams 2-chloro-4-methyl-5-nitrobenzamide, 21.4 grams methyltetradecylamine and 46.0 ml triethylamine was heated on a steam bath for 20 hours. The mixture was poured into about 200 ml ice water and made acid with concentrated HCl to a pH of 2-3. The mixture was filtered, washed with water and vacuum dried. The crude material was recrystallized from ethanol to give 30 grams product. m.p. = 117°-119°.