Methyl 8-methylsulfonyl-11-(1-acetoxycyclohexyl)-10-undecynoate → 8-Methylsulfonyl-11-(1-hydroxycyclohexyl)-10-undecynoic acid
反応式
[CH3:1][S:2]([CH:5]([CH2:16][CH2:17][CH2:18][CH:19]([O:25]C(=O)C)[CH2:20][CH2:21][CH2:22][CH2:23][CH3:24])[CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][C:12]([O:14]C)=[O:13])(=[O:4])=[O:3].CS(C(CC#CC1(OC(=O)C)CCCCC1)CCCCCCC(OC)=O)(=O)=O>>[CH3:1][S:2]([CH:5]([CH2:16][C:17]#[C:18][C:19]1([OH:25])[CH2:20][CH2:21][CH2:22][CH2:23][CH2:24]1)[CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][C:12]([OH:14])=[O:13])(=[O:3])=[O:4]参加物
3
実験手順
The synthesis of this compound is carried out by the procedure of Example 3, Step E, except that methyl 8-methylsulfonyl-12-acetoxyheptadecanoate is replaced by an equivalent quantity of methyl 8-methylsulfonyl-11-(1-acetoxycyclohexyl)-10-undecynoate.
後処理
- customThe synthesis of this compound