Hydrogen Peroxide → HCID 178425939、化合物

反応式

[C:1]([N:3]=[C:4]([S-:6])[S-:5])#[N:2].[K+].[K+].[CH3:9][C:10]1[CH:17]=[CH:16][C:13]([CH2:14]Cl)=[CH:12][CH:11]=1.[OH:18]O>>[OH:18][C:1]1[N:3]=[C:4]([S:6][CH2:9][C:10]2[CH:17]=[CH:16][C:13]([CH3:14])=[CH:12][CH:11]=2)[S:5][N:2]=1

参加物

反応物 3

HCID 784Hydrogen Peroxide

HCID 77224-Methylbenzyl chloride

HCID 83179Carbamodithioic acid, N-cyano-, potassium salt (1:2)

生成物 1

HCID 178425939HCID 178425939、化合物

実験手順

Using the procedure of Example 12, 58.2 g of dipotassium N-cyanodithioimidocarbonate and 42 g of p-methylbenzyl chloride were reacted and then were treated with 35 ml of 30% hydrogen peroxide to obtain 26 g of 3-hydroxy-5-p-methylbenzylthio-1,2,4-thiadiazole melting at 144° C.