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Carbon Disulfide → (2-{[(5-Methyl-1H-imidazol-4-yl)methyl]sulfanyl}ethyl)carbamodithioic acid
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Carbon Disulfide | HCID 6348 | — |
| 反応物 | HCID 178433288 | HCID 178433288 | — |
| 溶媒 | Ethanol | HCID 702 | — |
| 生成物 | (2-{[(5-Methyl-1H-imidazol-4-yl)methyl]sulfanyl}ethyl)carbamodithioic acid | HCID 15566013 | — |
反応手順
A solution of 4-methyl-5-((2-aminoethyl)thiomethyl) imidazole (10.2 g) in ethanol(75 ml) was added slowly, with stirring, to carbon disulphide (200 ml). The mixture was set aside overnight at room temperature and the solid formed was collected and recystallised from aqueous isopropyl alcohol to afford N-[2-((5-methyl-4imidazolyl)methylthio)ethyl]dithiocarbamic acid (9.8 g)., m.p. 127°-129°.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04070472 |
| 出典データセット | uspto-grants-1978_01 |
| ORD ID | ord-4c908ea815e94302afee9727e4d82d92 |
| 出典メモ | uspto-grants-1978_01 |