関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | 3-(3-Nitro-phenyl)-acrylonitrile | HCID 55669 | — |
| 触媒 | Chlorotris(triphenylphosphine)rhodium(I) | HCID 84599 | — |
| 溶媒 | Benzene | HCID 241 | — |
| 生成物 | 3-(3-Nitro-phenyl)-propionitrile | HCID 22186098 | — |
反応手順
There are introduced into a cylinder 3 g of the product obtained in Step 1, 1.59 g of tris(triphenylphosphine)rhodium(I) chloride and 90 ml of benzene. The whole is heated for 5 hours at 40° C. under a hydrogen pressure of 5 bar. The solvent is evaporated off and the residue is purified by chromatography on silica gel using dichloromethane as eluant.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US06784183B2 |
|---|
| 出典データセット | uspto-grants-2004_08 |
|---|
| ORD ID | ord-85e8aacf647b40d99e6441bc79a44ef9 |
|---|
| 出典メモ | uspto-grants-2004_08 |
|---|
