1-Iodononane → 6-Acetyl-4,4-dimethyl-1-nonyl-3,4-dihydroquinolin-2(1H)-one

反応式

[CH2:1]([N:7]1[C:16]2[C:11](=[CH:12][C:13]([C:17](=[O:19])[CH3:18])=[CH:14][CH:15]=2)[C:10]([CH3:21])([CH3:20])[CH2:9][C:8]1=[O:22])[CH2:2][CH2:3][CH2:4][CH2:5][CH3:6].I[CH2:24][CH2:25][CH2:26]CCCCCC>>[CH2:1]([N:7]1[C:16]2[C:11](=[CH:12][C:13]([C:17](=[O:19])[CH3:18])=[CH:14][CH:15]=2)[C:10]([CH3:21])([CH3:20])[CH2:9][C:8]1=[O:22])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:24][CH2:25][CH3:26]

参加物

反応物 2

HCID 202751-Iodononane

HCID 121354162(1H)-Quinolinone, 6-acetyl-1-hexyl-3,4-dihydro-4,4-dimethyl-

生成物 1

HCID 234447006-Acetyl-4,4-dimethyl-1-nonyl-3,4-dihydroquinolin-2(1H)-one

実験手順

Following a procedure similar to that used for the preparation of Intermediate 6a but using 1-iodo-n-nonane as the alkylating reagent the title compound was obtained as a colorless oil (70% yield).

出典と根拠

ORDレコード: ord-6d93beeb9cb142329ec0c32b2b358192
出典データセット: uspto-grants-2004_01
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US06683092B1

反応ノート

読み込み中…