Hydrogen Peroxide → 6-hydroxy-4-methylbenzo[d]oxazol-2(3H)-one

HRID 1846417ノート

反応式

HRID 1846417 の反応式
[CH3:1][C:2]1[C:7]2[NH:8][C:9](=[O:11])[O:10][C:6]=2[CH:5]=[C:4]([O:12]B(O)O)[CH:3]=1.OO>C(O)(=O)C>[OH:12][C:4]1[CH:3]=[C:2]([CH3:1])[C:7]2[NH:8][C:9](=[O:11])[O:10][C:6]=2[CH:5]=1

参加物

4

反応物 2

HCID 784Hydrogen PeroxideHCID 669782724-Methyl-2-oxo-2,3-dihydrobenzo[d]oxazol-6-ylboric acid

生成物 1

HCID 669780936-hydroxy-4-methylbenzo[d]oxazol-2(3H)-one

試薬・触媒・溶媒 1

HCID 176Acetic Acid溶媒

実験手順

77 mg (0.40 mmol) 4-methyl-2-oxo-2,3-dihydrobenzo[d]oxazol-6-ylboric acid were dissolved in 2.0 mL glacial acetic acid and mixed with 0.20 mL (2.3 mmol) hydrogen peroxide solution (35% in water) and stirred briefly. The reaction mixture was left to stand for 1 h at RT. The precipitate formed was suction filtered, washed with water and dried i. vac.

後処理

  1. waitThe reaction mixture was left
  2. customThe precipitate formed
  3. filtrationfiltered
  4. washwashed with water
  5. customdried i

出典と根拠

ORDレコード
ord-ae0a62c06edc422f8e8d1e65b131a93d
出典データセット
uspto-grants-2015_02
特許番号
US08952014B2

反応ノート

読み込み中…