(4-Methoxyphenyl)(naphthalen-2-yl)methanone → HCID 15640646、化合物
反応式
[CH:1]1[C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[CH:4]=[CH:3][C:2]=1[C:11]([C:13]1[CH:18]=[CH:17][C:16]([O:19]C)=[CH:15][CH:14]=1)=[O:12].C[S-].[Na+]>CN(C)C=O>[CH:1]1[C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[CH:4]=[CH:3][C:2]=1[C:11]([C:13]1[CH:14]=[CH:15][C:16]([OH:19])=[CH:17][CH:18]=1)=[O:12]参加物
4
実験手順
4-Methoxyphenyl 2-naphthyl ketone (735 mg) obtained in Example 35 was dissolved in N,N-dimethylformamide (20 ml), sodium thiomethoxide (491 mg) was added, and the admixture was refluxed under argon for 5 hours. The reaction mixture was treated in the same manner as described in Example 33 to obtain 595 mg of the title compound (yield: 86%).
後処理
- temperaturethe admixture was refluxed under argon for 5 hours
- additionThe reaction mixture was treated in the same manner
出典と根拠
- ORDレコード
- ord-0b6e6f7945f146d7a0d08b4d122512c5
- 出典データセット
- uspto-grants-2000_11
- 特許番号
- US06143764
反応ノート
読み込み中…