2,4-Dimethylpent-2-ene → HCID 22129039、化合物

HRID 1858396ノート

反応式

HRID 1858396 の反応式
[CH3:1][CH:2]([CH:4]=[C:5]([CH3:7])[CH3:6])[CH3:3].[Cl:8][SiH:9]([Cl:11])[Cl:10].N(C1(C#N)CCCCC1)=NC1(C#N)CCCCC1>>[CH3:6][CH:5]([CH:4]([Si:9]([Cl:11])([Cl:10])[Cl:8])[CH:2]([CH3:3])[CH3:1])[CH3:7]

参加物

4

反応物 3

HCID 122602,4-Dimethylpent-2-eneHCID 24811TrichlorosilaneHCID 749781,1'-Azobis(cyclohexanecarbonitrile)

生成物 1

HCID 22129039HCID 22129039、化合物収率 89.3%

実験手順

A one-liter autoclave equipped with a stirrer was charged in a nitrogen atmosphere with 55 grams (0.56 mol) of 2,4-dimethyl-3-pentene, 148 grams (1.1 mol) of trichlorosilane and 17 grams (70 mmols) of 1,1'-azobis(cyclohexane-1-carbonitrile) and the mixture was reacted at a temperature of 130° C. for 4 days. The resulting reaction mixture was purified by distillation thereby obtaining 117 grams (0.50 mol) of 2,4-dimethyl-3-trichlorosilylpentane. The structure of the resulting product was identified by 1HNMR.

後処理

  1. customA one-liter autoclave equipped with a stirrer
  2. customthe mixture was reacted at a temperature of 130° C. for 4 days
  3. customThe resulting reaction mixture
  4. distillationwas purified by distillation

出典と根拠

ORDレコード
ord-18b16a5cd7f742419e33d5ce4be60108
出典データセット
uspto-grants-2000_11
特許番号
US06150549

反応ノート

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