Trichlorosilane → HCID 57078977、化合物

HRID 1858399ノート

反応式

HRID 1858399 の反応式
[CH3:1][C:2]1[CH2:7][CH2:6][CH2:5][CH:4]([CH3:8])[CH:3]=1.[Cl:9][SiH:10]([Cl:12])[Cl:11].N(C1(C#N)CCCCC1)=NC1(C#N)CCCCC1>>[CH3:1][CH:2]1[CH2:7][CH:6]([Si:10]([Cl:12])([Cl:11])[Cl:9])[CH2:5][CH:4]([CH3:8])[CH2:3]1

参加物

4

反応物 3

HCID 24811TrichlorosilaneHCID 749781,1'-Azobis(cyclohexanecarbonitrile)HCID 1377261,3-Dimethyl-1-cyclohexene

生成物 1

HCID 57078977HCID 57078977、化合物収率 80%

実験手順

A one-liter autoclave equipped with a stirrer was charged in a nitrogen atmosphere with 39 grams (0.35 mol) of 1,3-dimethylcyclohexene, 94 grams (0.69 mol) of trichlorosilane and 18 grams (74 mmol) of 1,1'-azobis(cydohexane-1-carbonitrile) and the mixture was reacted at a temperature of 130° C. for 3 days. The resulting reaction mixture was purified by distillation thereby obtaining 69 grams (0.28 mol) of 2,6-dimethyl-4-cyciohexyltrichlorosilane, The structure of the resulting product was Identified by 1H-NMR analysis.

後処理

  1. customA one-liter autoclave equipped with a stirrer
  2. customthe mixture was reacted at a temperature of 130° C. for 3 days
  3. customThe resulting reaction mixture
  4. distillationwas purified by distillation

出典と根拠

ORDレコード
ord-8e7e12bbef7e4f5f99d161d577317151
出典データセット
uspto-grants-2000_11
特許番号
US06150549

反応ノート

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