Dimethylformamide dimethyl acetal → HCID 20291411、化合物
反応式
[CH3:1]OC(OC)N(C)C.[CH3:9][C:10]1[N:11]=[C:12]([C:20]2[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=2)[N:13]2[C:18]=1[CH:17]=[N:16][NH:15][C:14]2=[O:19]>C1C=CC=CC=1>[CH3:1][N:15]1[C:14](=[O:19])[N:13]2[C:12]([C:20]3[CH:21]=[CH:22][CH:23]=[CH:24][CH:25]=3)=[N:11][C:10]([CH3:9])=[C:18]2[CH:17]=[N:16]1参加物
4
実験手順
Dimethylformamide dimethyl acetal (0.73 ml.; d=0.087, 0.005 mole) is added slowly to a slurry of 8-methyl-6-phenylimidazo[1,5-d]-as-triazin-4(3H)-one (1.13 gm., 0.005 mole) in benzene (25 ml.). The reaction mixture is stirred, refluxed for 24 hours, cooled and filtered. The filtrate is evaporated to yield 1.4 gm. (100%) product. Recrystallization from methyl cyclohexane yields yellow crystals, found to be identical (ir; nmr) to the product obtained by Method A.