Diazomethane → Methyl-4-iodocinnamate

HRID 1869824ノート

反応式

HRID 1869824 の反応式
[I:1][C:2]1[CH:12]=[CH:11][C:5]([CH:6]=[CH:7][C:8]([OH:10])=[O:9])=[CH:4][CH:3]=1.[N+](=[CH2:15])=[N-]>CO.C(OCC)C>[CH3:15][O:9][C:8](=[O:10])[CH:7]=[CH:6][C:5]1[CH:4]=[CH:3][C:2]([I:1])=[CH:12][CH:11]=1

参加物

5

反応物 2

HCID 9550DiazomethaneHCID 35997884-Iodocinnamic acid

生成物 1

HCID 582796Methyl-4-iodocinnamate

試薬・触媒・溶媒 2

HCID 887Methanol溶媒HCID 3283Diethyl Ether溶媒

実験手順

A stirred, cooled (ice bath) solution of 4-iodo-cinnamic acid in methanol was treated with a solution of diazomethane in diethyl ether. The reaction mixture was allowed to warm to ambient temperature, the volatiles were evaporated in vacuo to afford the title compound.

後処理

  1. customthe volatiles were evaporated in vacuo

出典と根拠

ORDレコード
ord-42cf8e4d98564c9a94dbd28a55a7d7ba
出典データセット
uspto-grants-2009_12
特許番号
US07638648B2

反応ノート

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