関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | 2-Benzoylbenzoic Acid | HCID 6813 | — |
| 反応物 | Triphenylbismuth | HCID 11774 | — |
| 反応物 | 1,4-Dioxane | HCID 31275 | — |
| 生成物 | Bismuth(III)benzoyl benzoate | HCID 86645404 | — |
反応手順
In a dry three-neck-flask, 1.5 g (3.4 mmol) triphenylbismuth dissolved in 5 ml dioxane is added to a solution of 2.31 g (10.2 mmol) benzoylbenzoic acid in 3 ml dioxane under argon and the resulting solution is heated to 110° C. for 1.5 hours. The mixture is cooled to room temperature and concentrated yielding 1.5 g of the product. The structure is confirmed by 1H-NMR and 13C-NMR spectra.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US08318830B2 |
|---|
| 出典データセット | uspto-grants-2012_11 |
|---|
| ORD ID | ord-efebecdbd6694996a96e921215422c81 |
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| 出典メモ | uspto-grants-2012_11 |
|---|
