Ammonia → (+/-)-Abscisic acid

HRID 1882183

反応式

HRID 1882183 の反応式
[CH3:1][C:2]1[C@:8]([OH:17])(/[CH:9]=[CH:10]/[C:11](/[CH3:16])=[CH:12]\[C:13]([OH:15])=[O:14])[C:7]([CH3:19])([CH3:18])[CH2:6][C:4](=[O:5])[CH:3]=1.[OH-].[K+].N.C([O-])(=O)/C=C/C=C/C.[K+]>O>[CH3:1][C:2]1[C:8]([OH:17])(/[CH:9]=[CH:10]/[C:11](/[CH3:16])=[CH:12]\[C:13]([OH:15])=[O:14])[C:7]([CH3:19])([CH3:18])[CH2:6][C:4](=[O:5])[CH:3]=1

参加物

6

反応物 4

HCID 222AmmoniaHCID 14797Potassium HydroxideHCID 5280896Abscisic AcidHCID 23676745Potassium Sorbate

生成物 1

HCID 5375199(+/-)-Abscisic acid

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

(S)-(+)-Abscisic acid (2.64 g of 95% purity) was suspended in 15 mL of deionized water containing 50 mg of Tween 20. One quarter of the theoretical amount of potassium hydroxide (250 microL of 10.0 molar aqueous solution) was added. The remainder of the neutralization was then carried out with concentrated aqueous ammonia solution, to give a clear solution of pH 7.1. Preservative (63 mg of potassium sorbate) was added, and it quickly dissolved. The solution was made up to 25 mL final volume to give a 10% by weight aqueous composition of abscisic acid as a mixture of the ammonium and potassium salts.

後処理

  1. customto give a clear solution of pH 7.1
  2. dissolutionit quickly dissolved

出典と根拠

ORDレコード
ord-f2fd709f55464c6193b3cb8ac0b56f91
出典データセット
uspto-grants-2012_11
特許番号
US08318976B2

関連ノート

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