(+)-2-Octanol → HCID 22845783、化合物

反応式

C[C:2]1[CH:10]=[CH:9][C:5]([C:6]([OH:8])=[O:7])=[C:4](OCCC)[N:3]=1.[CH3:15][C@H:16]([OH:23])[CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22]>>[CH3:15][C@H:16]([O:23][C:2]1[CH:10]=[CH:9][C:5]([C:6]([OH:8])=[O:7])=[CH:4][N:3]=1)[CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22]

参加物

反応物 2

HCID 2723888(+)-2-Octanol

HCID 62702426HCID 62702426、化合物

生成物 1

HCID 22845783HCID 22845783、化合物

実験手順

The same procedure followed for the methylpropyloxynicotinic acid was used employing 1(S)-methylheptanol as the starting alcohol. A quantitative yield of 6-(1(S)methylheptyloxy)nicotinic acid (2, where R2 is 1(S)-methylheptyl was obtained as a brownish solid. The material was used without further purification.

出典と根拠

ORDレコード: ord-c014afc5497e4bccbec12d8c8f5d5196
出典データセット: uspto-grants-1992_09
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US05145601

反応ノート

読み込み中…