Gallium, chlorodimethyl- → (3-Dimethylarsinopropyl)-dimethylgallium

HRID 1886210ノート

反応式

HRID 1886210 の反応式
[CH3:1][As:2]([CH3:7])[CH2:3][CH2:4][CH2:5]Cl.[Mg].[Cl-].[CH3:10][Ga+:11][CH3:12]>C(OCC)C>[CH3:1][As:2]([CH3:7])[CH2:3][CH2:4][CH2:5][Ga:11]([CH3:12])[CH3:10]

参加物

5

反応物 3

HCID 81329Gallium, chlorodimethyl-HCID 5462224MagnesiumHCID 85772197(3-Dimethylarsinopropyl)chloride

生成物 1

HCID 86745768(3-Dimethylarsinopropyl)-dimethylgallium

試薬・触媒・溶媒 1

HCID 3283Diethyl Ether溶媒2 回

実験手順

5.47 g (30 mmol) of (3-dimethylarsinopropyl)chloride are added to 1.44 g (60 mmol) of magnesium chips in 100 ml of diethylether at 20° C., and then the mixture is heated under reflux for two hours. The solution is allowed to come to room temperature, 4.0 g (30 mmol) of dimethylgallium chloride is 50 ml of diethylether are added, and the solution is refluxed again for two hours. The working up is carried out analogously to Example 1. (3-Dimethylarsinopropyl)-dimethylgallium is obtained as a clear liquid with a B.p. of 86° C./0.01 mbar.

後処理

  1. temperaturethe mixture is heated
  2. temperatureunder reflux for two hours
  3. customto come to room temperature
  4. additionare added
  5. temperaturethe solution is refluxed again for two hours

出典と根拠

ORDレコード
ord-534f2af40de14452a7b4c3316242336a
出典データセット
uspto-grants-1992_09
特許番号
US05149853

反応ノート

読み込み中…