tert-Butyl hydroperoxide → Tris-(4-benzoyloxy-2,2,6,6-tetramethyl-piperidin-1-yloxy)octadecane

HRID 1900303

反応式

HRID 1900303 の反応式
[C:1]([O:9][CH:10]1[CH2:15][C:14]([CH3:17])([CH3:16])[N:13]([OH:18])[C:12]([CH3:20])([CH3:19])[CH2:11]1)(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[C:21]([O:25]O)([CH3:24])([CH3:23])C.[CH3:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH3:44]>[Mo](=O)(=O)=O>[C:1]([O:9][CH:10]1[CH2:11][C:12]([CH3:20])([CH3:19])[N:13]([O:18][C:44]([O:18][N:13]2[C:12]([CH3:20])([CH3:19])[CH2:11][CH:10]([O:9][C:1](=[O:8])[C:2]3[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=3)[CH2:15][C:14]2([CH3:16])[CH3:17])([O:18][N:13]2[C:14]([CH3:16])([CH3:15])[CH2:24][CH:21]([O:25][C:1](=[O:8])[C:2]3[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=3)[CH2:23][C:12]2([CH3:19])[CH3:11])[CH2:43][CH2:42][CH2:41][CH2:40][CH2:39][CH2:38][CH2:37][CH2:36][CH2:35][CH2:34][CH2:33][CH2:32][CH2:31][CH2:30][CH2:29][CH2:28][CH3:27])[C:14]([CH3:16])([CH3:17])[CH2:15]1)(=[O:8])[C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1

参加物

5

反応物 3

HCID 6410tert-Butyl hydroperoxideHCID 11635OctadecaneHCID 6881781-Hydroxy-4-benzoyloxy-2,2,6,6-tetramethylpiperidine

生成物 1

HCID 23372129Tris-(4-benzoyloxy-2,2,6,6-tetramethyl-piperidin-1-yloxy)octadecane

試薬・触媒・溶媒 1

HCID 14802Molybdenum trioxide触媒

実験手順

A mixture of 80 mmol of 4-benzoyloxy-1-oxyl-2,2,6,6-tetramethylpiperidine, 250 mmol of 90% tert-butyl hydroperoxide, 125 grams of octadecane and 5 mmol of molybdenum trioxide is heated ait 140° C. in a Fischer-Porter prerssure bottle till the red color of the N-oxyl compound is no longer visible. The reaction mixture is purified by flash chromatography.

後処理

  1. customThe reaction mixture is purified by flash chromatography

出典と根拠

ORDレコード
ord-e5bd1ca60c204db99c67898a5739116e
出典データセット
uspto-grants-1996_11
特許番号
US05574162

関連ノート

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