Acetone → N-[(4,6-Dimethoxy-1,3,5-triazin-2-yl)aminocarbonyl]-2-pyridinesulfonamide

反応式

[CH3:1][O:2][C:3]1[N:8]=[C:7]([O:9][CH3:10])[N:6]=[C:5]([NH:11][C:12](=S)[NH:13][S:14]([C:17]2[CH:22]=[CH:21][CH:20]=[CH:19][N:18]=2)(=[O:16])=[O:15])[N:4]=1.CC(C)=[O:26]>>[CH3:1][O:2][C:3]1[N:8]=[C:7]([O:9][CH3:10])[N:6]=[C:5]([NH:11][C:12]([NH:13][S:14]([C:17]2[CH:22]=[CH:21][CH:20]=[CH:19][N:18]=2)(=[O:16])=[O:15])=[O:26])[N:4]=1

参加物

反応物 2

HCID 180Acetone

HCID 20278358HCID 20278358、化合物

生成物 1

HCID 20278363N-[(4,6-Dimethoxy-1,3,5-triazin-2-yl)aminocarbonyl]-2-pyridinesulfonamide

実験手順

A mixture containing 2.7 g of N-[(4,6-dimethoxy-1,3,5-triazin-2-yl)aminothioxomethyl]-2-pyridinesulfonamide, 2.98 g of mercuric oxide and 75 ml of acetone is stirred at ambient temperature for 60 hours and then filtered. Evaporation of the filtrate in vacuo yields the desired product.

後処理

filtrationfiltered
customEvaporation of the filtrate in vacuo

出典と根拠

ORDレコード: ord-575162ea759b46d7baad286a958d328e
出典データセット: uspto-grants-1984_03
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US04435206

反応ノート

読み込み中…

参加物