Acetic Acid → 2-(2,4-Dihydroxyphenyl)-2-methyl-heptane

HRID 1904030ノート

反応式

HRID 1904030 の反応式
C(O)(=O)C.S(=O)(=O)(O)O.[C:10]1([CH:17]=[CH:16][CH:15]=[C:13]([OH:14])[CH:12]=1)[OH:11].O[C:19]([CH3:26])([CH2:21][CH2:22][CH2:23][CH2:24][CH3:25])[CH3:20]>O>[OH:11][C:10]1[CH:12]=[C:13]([OH:14])[CH:15]=[CH:16][C:17]=1[C:19]([CH3:26])([CH2:21][CH2:22][CH2:23][CH2:24][CH3:25])[CH3:20]

参加物

6

反応物 4

HCID 176Acetic AcidHCID 1118Sulfuric AcidHCID 5054ResorcinolHCID 122422-Methyl-2-heptanol

生成物 1

HCID 204660772-(2,4-Dihydroxyphenyl)-2-methyl-heptane

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

To 100 parts of glacial acetic acid containing 9.8 parts of 98% sulphuric acid was added 22 parts of resorcinol followed by 13 parts of 2-hydroxy-2-methyl-heptane at room temperature. After storing overnight at the same temperature the reaction mixture was poured into 1000 parts of water. The organic phase which separated out, was after decanting off the water, taken up in ether, washed with sodium bicarbonate solution, and finally with water. The ether solution was then evaporated and the residue distilled to give 2-(2,4-dihydroxyphenyl)-2-methyl-heptane (compound of the formula (4)) with a boiling point (b.p.12) of from 202°-204° C. and with the following percentage composition by weight:

後処理

  1. customThe organic phase which separated out
  2. customafter decanting off the water
  3. washwashed with sodium bicarbonate solution
  4. customThe ether solution was then evaporated
  5. distillationthe residue distilled

出典と根拠

ORDレコード
ord-4d9d9cf5a3f94ff6ba55704b13268e60
出典データセット
uspto-grants-1984_03
特許番号
US04439518

反応ノート

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