Triphenylphosphine → HCID 20039288、化合物

HRID 1904502

反応式

HRID 1904502 の反応式
[C:1]1([P:7]([C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=2)[C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[N+:20]([C:23]1[CH:28]=[CH:27][C:26]([S:29]([O:32]C)(=[O:31])=[O:30])=[CH:25][CH:24]=1)([O-:22])=[O:21]>>[N+:20]([C:23]1[CH:24]=[CH:25][C:26]([S:29]([O-:32])(=[O:30])=[O:31])=[CH:27][CH:28]=1)([O-:22])=[O:21].[CH3:23][P+:7]([C:1]1[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1)([C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1)[C:14]1[CH:15]=[CH:16][CH:17]=[CH:18][CH:19]=1

参加物

3

反応物 2

HCID 11776TriphenylphosphineHCID 22582Methyl-4-nitrobenzenesulfonate

生成物 1

HCID 20039288HCID 20039288、化合物収率 187%

実験手順

A mixture of 5.83 g (22.2 mmol) of triphenylphosphine and 5.00 g (23.0 mmol) methyl 4-nitrobenzenesulfonate was allowed to react for 2 hrs at 145° C. A total of 10.3 g (21.5 mmol, 96.8%) of the product was obtained, which was further purified by recrystallization from 90:10 toluene-acetonitrile.

後処理

  1. customto react for 2 hrs at 145° C

出典と根拠

ORDレコード
ord-4b2dc9e4efbc468a93c166b6b04d5240
出典データセット
uspto-grants-1989_06
特許番号
US04837391

関連ノート

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