Methyl fluorosulfate → 4-Cyano-3,5-dichloro-2-methylisothiazolium fluorosulfonate
反応式
[C:1]([C:3]1[C:4]([Cl:9])=[N:5][S:6][C:7]=1[Cl:8])#[N:2].[F:10][S:11]([O:14][CH3:15])(=[O:13])=[O:12]>>[F:10][S:11]([O-:14])(=[O:13])=[O:12].[C:1]([C:3]1[C:4]([Cl:9])=[N+:5]([CH3:15])[S:6][C:7]=1[Cl:8])#[N:2]参加物
3
実験手順
4-Cyano-3,5-dichloroisothiazole (5.0 g, 0.028 mol) and 4 ml of methyl fluorosulfonate were heated at 80°-90° for 30 min under a nitrogen atmosphere. The resulting solid was washed with ether and benzene to yield 7.5 g (92%) of 4-cyano-3,5-dichloro-2-methylisothiazolium fluorosulfonate, mp 160-170. Spectral data (NMR and IR) were consistent with the assigned structure. Analysis calculated for C5H3Cl2FN2O3S2 : C, 20.50; H, 1.02; Found: C, 20.27; H, 1.44.
後処理
- washThe resulting solid was washed with ether and benzene
出典と根拠
- ORDレコード
- ord-7357dc6e5b764b5fb7c5d652dbdde253
- 出典データセット
- uspto-grants-1989_06
- 特許番号
- US04841063
反応ノート
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