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2-Methyl-3,4,5-trichloroisothiazolium fluorosulfonate → 4,5-Dichloro-2-methyl-4-isothiazolin-3-one
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 2-Methyl-3,4,5-trichloroisothiazolium fluorosulfonate | HCID 12889022 | — |
| 溶媒 | Sodium Acetate | HCID 517045 | — |
| 生成物 | 4,5-Dichloro-2-methyl-4-isothiazolin-3-one | HCID 147017 | 70.3% |
反応手順
2-Methyl-3,4,5-trichloroisothiazolium fluorosulfonate (16.9 g, 0.058 mol) was added in portions to 150 ml of a saturated sodium acetate solution. After stirring for 30 min. the solid was collected, washed with water, and recrystallized from ethanol to yield 7.5 g (70%) of 4,5-dichloro-2-methyl-4-isothiazolin-3-one, mp 119°-120°.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04841063 |
| 出典データセット | uspto-grants-1989_06 |
| ORD ID | ord-050adf1464da402db63ddf428a50432a |
| 出典メモ | uspto-grants-1989_06 |