3-methoxy-6-methyl-4-nitropyridazine 1-oxide → HCID 21766149、化合物

HRID 1907822ノート

反応式

HRID 1907822 の反応式
[CH3:1][O:2][C:3]1[N:4]=[N+:5]([O-:13])[C:6]([CH3:12])=[CH:7][C:8]=1[N+]([O-])=O.[CH3:14][O-:15].[Na+]>CO>[CH3:1][O:2][C:3]1[N:4]=[N+:5]([O-:13])[C:6]([CH3:12])=[CH:7][C:8]=1[O:15][CH3:14]

参加物

4

反応物 2

HCID 64053053-methoxy-6-methyl-4-nitropyridazine 1-oxideHCID 10942334Sodium Methoxide

生成物 1

HCID 21766149HCID 21766149、化合物

試薬・触媒・溶媒 1

HCID 887Methanol溶媒

実験手順

3-Methoxy-6-methyl-4-nitropyridazine 1-oxide (1 g) was converted and worked up analogously to example 1 g). Chromatography of the crude product was unnecessary. The solvent used was methanol (30 ml), and the base sodium methoxide (as 30% solution in methanol, 1.1 ml). Yield: 900 mg LC-MS Rt: 0.29 min [M+H]+:171.1

出典と根拠

ORDレコード
ord-73fa67287c55470cb6a518fcc5adc71e
出典データセット
uspto-grants-2013_12
特許番号
US08598177B2

反応ノート

読み込み中…