Trimethylsilyldiazomethane → HCID 86657035、化合物
反応式
[Cl:1][C:2]1[CH:3]=[C:4]([CH:8]=[C:9]([C:11]([CH3:13])=[CH2:12])[N:10]=1)[C:5]([OH:7])=[O:6].[N+](=[CH:16][Si](C)(C)C)=[N-]>ClCCl.CO>[Cl:1][C:2]1[CH:3]=[C:4]([CH:8]=[C:9]([C:11]([CH3:13])=[CH2:12])[N:10]=1)[C:5]([O:7][CH3:16])=[O:6]参加物
5
実験手順
To a solution of 2-chloro-6-isopropenylisonicotinic acid (0.25 g, 1.27 mmol) in dichloromethane (4.7 mL) and methanol (1.6 mL) was added (diazomethyl)(trimethyl)silane (0.63 mL, 1.27 mmol). After the addition, the mixture was concentrated and carried onto the next step. MS 212.0 (M+1).
後処理
- additionAfter the addition
- concentrationthe mixture was concentrated
出典と根拠
- ORDレコード
- ord-2d08f2d3334a4f7a87fc2643116b1aef
- 出典データセット
- uspto-grants-2013_12
- 特許番号
- US08598209B2
反応ノート
読み込み中…