Potassium Carbonate → Ethyl 4-(benzyloxy)-3-hydroxybenzoate

HRID 1918318ノート

反応式

HRID 1918318 の反応式
[CH2:1]([O:3][C:4](=[O:23])[C:5]1[CH:10]=[CH:9][C:8]([O:11][CH2:12][C:13]2[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=2)=[C:7]([O:19]C(=O)C)[CH:6]=1)[CH3:2].C(=O)([O-])[O-].[K+].[K+]>CO>[CH2:1]([O:3][C:4](=[O:23])[C:5]1[CH:10]=[CH:9][C:8]([O:11][CH2:12][C:13]2[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=2)=[C:7]([OH:19])[CH:6]=1)[CH3:2]

参加物

4

反応物 2

HCID 11430Potassium CarbonateHCID 67170201HCID 67170201、化合物

生成物 1

HCID 11311797Ethyl 4-(benzyloxy)-3-hydroxybenzoate

試薬・触媒・溶媒 1

HCID 887Methanol溶媒

実験手順

The compound of step 2 (10 g, 31.8 mmol) was dissolved in methanol, potassium carbonate (88 mg, 0.636 mmol) was added and the mixture was stirred for 2 h under reflux. The solution was evaporated to dryness and the residue used without further purification.

後処理

  1. temperatureunder reflux
  2. customThe solution was evaporated to dryness
  3. customthe residue used without further purification

出典と根拠

ORDレコード
ord-8b32513e163d4143a66e1a137d6b959b
出典データセット
uspto-grants-2013_12
特許番号
US08618304B2

反応ノート

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