Cyclohexanone, 4,4-dimethyl- → 2-(Diethoxymethyl)-4,4-dimethylcyclohexanone

反応式

[CH3:1][C:2]1([CH3:9])[CH2:7][CH2:6][C:5](=[O:8])[CH2:4][CH2:3]1.F[B-](F)(F)F.[CH2:15]([O:17][CH+:18][O:19][CH2:20][CH3:21])[CH3:16]>>[CH2:15]([O:17][CH:18]([O:19][CH2:20][CH3:21])[CH:4]1[CH2:3][C:2]([CH3:9])([CH3:1])[CH2:7][CH2:6][C:5]1=[O:8])[CH3:16]

参加物

反応物 2

HCID 138166Cyclohexanone, 4,4-dimethyl-

HCID 178468207HCID 178468207、化合物

生成物 1

HCID 580183412-(Diethoxymethyl)-4,4-dimethylcyclohexanone

実験手順

reacting 4,4-dimethylcyclohexanone, diethoxycarbenium fluoroborate and a fifth base to provide (2-(diethoxymethyl)-4,4-dimethylcyclohexanone and isolating or not isolating the 2-(diethoxymethyl)-4,4-dimethylcyclohexanone;

出典と根拠

ORDレコード: ord-48d4a885542e436ca518e7ee5d301f82
出典データセット: uspto-grants-2012_05
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US08168784B2

反応ノート

読み込み中…