2,5-Furandimethanol → 2,5-Tetrahydrofurandimethanol

HRID 1921603

反応式

HRID 1921603 の反応式
[OH:1][CH2:2][C:3]1[O:7][C:6]([CH2:8][OH:9])=[CH:5][CH:4]=1.[H][H]>[Ni].C(O)C>[OH:9][CH2:8][CH:6]1[O:7][CH:3]([CH2:2][OH:1])[CH2:4][CH2:5]1

参加物

5

反応物 2

HCID 746632,5-FurandimethanolHCID 178418361HCID 178418361、化合物

生成物 1

HCID 977922,5-Tetrahydrofurandimethanol

試薬・触媒・溶媒 2

HCID 935Nickel触媒HCID 702Ethanol溶媒

実験手順

Raney nickel [ethanol was added three times to 50% commercial aqueous Raney nickel suspension (5 mL) from Acros, and decanted] was added to a solution of (5-hydroxymethylfuran-2-yl)methanol (RK-325) (3.46 g, 27 mmol) in absolute ethanol (100 mL), and hydrogenated overnight at room temperature and at a pressure of 2 bar (hydrogen consumption 61 mmol). The reaction mixture was filtered and the filtrate was concentrated under vacuum.

後処理

  1. filtrationThe reaction mixture was filtered
  2. concentrationthe filtrate was concentrated under vacuum

出典と根拠

ORDレコード
ord-7cb275e0c6744cc492427a38fcf243d7
出典データセット
uspto-grants-2012_05
特許番号
US08173700B2

関連ノート

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