3-Phenyl-3,4-dihydro-1(2h)-naphthalenone → 1-Benzyl-5-(3-phenyl-3,4-dihydro-2H-naphthalen-1-ylidenemethyl)-1H-imidazole

HRID 1935758ノート

反応式

HRID 1935758 の反応式
[CH2:1]([N:8]1[C:12]([CH:13]=C2C3C(=CC=CC=3)CC2C2C=CC=CC=2)=[CH:11][N:10]=[CH:9]1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[C:29]1([CH:35]2[CH2:44][C:43]3[C:38](=[CH:39][CH:40]=[CH:41][CH:42]=3)[C:37](=O)[CH2:36]2)[CH:34]=[CH:33][CH:32]=[CH:31][CH:30]=1>>[CH2:1]([N:8]1[C:12]([CH:13]=[C:37]2[C:38]3[C:43](=[CH:42][CH:41]=[CH:40][CH:39]=3)[CH2:44][CH:35]([C:29]3[CH:34]=[CH:33][CH:32]=[CH:31][CH:30]=3)[CH2:36]2)=[CH:11][N:10]=[CH:9]1)[C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1

参加物

3

反応物 2

HCID 5765563-Phenyl-3,4-dihydro-1(2h)-naphthalenoneHCID 698316891-Benzyl-5-(2-phenylindan-1-ylidenemethyl)-1H-imidazole

生成物 1

HCID 698323401-Benzyl-5-(3-phenyl-3,4-dihydro-2H-naphthalen-1-ylidenemethyl)-1H-imidazole

実験手順

1-Benzyl-5-(3-phenyl-3,4-dihydro-2H-naphthalen-1-ylidenemethyl)-1H-imidazole was prepared as 1-benzyl-5-(2-phenylindan-1-ylidenemethyl)-1H-imidazole above except that 3-phenyl-3,4-dihydro-2H-naphthalen-1-one (prepared according to J. Vebrel and R. Carrie Bull. Soc. Chem. Fr. (1982) 116) was used as a starting material. The crude product as its hydrochloride salt was used in the next step without purification.

後処理

  1. customThe crude product as its hydrochloride salt was used in the next step without purification

出典と根拠

ORDレコード
ord-0e94f973d3c04c48978de6e9913b0df9
出典データセット
uspto-grants-2002_05
特許番号
US06388090B2

反応ノート

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