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1-Chlorooctane → Octyltrichlorosilane
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 1-Chlorooctane | HCID 8142 | — |
| 反応物 | Trichlorosilane | HCID 24811 | — |
| 触媒 | Tetrabutylphosphonium chloride | HCID 75311 | — |
| 生成物 | Octyltrichlorosilane | HCID 21354 | 85.2% |
反応手順
In the same apparatus and procedure as Example 1 above, 0.20 g (0.68 mmol) of tetrabutylphosphonium chloride, 1.00 g (6.73 mmol) of 1-chlorooctane and 2.71 g (20.0 mmol) of trichlorosilane were reacted at 170° C. for 2 hrs. The resulting mixture was distilled to give 1.42 g of n-octyltrichlorosilane (yield; 85%).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US06392077B1 |
| 出典データセット | uspto-grants-2002_05 |
| ORD ID | ord-d8381254d70d4b2bb3357e2f5531e2a3 |
| 出典メモ | uspto-grants-2002_05 |