Trichloro(chloromethyl)silane → Bis(trichlorosilyl)methane

HRID 1937077ノート

反応式

HRID 1937077 の反応式
[Cl-].C([P+](CCCC)(CCCC)CCCC)C1C=CC=CC=1.Cl[CH2:23][Si:24]([Cl:27])([Cl:26])[Cl:25].[Cl:28][SiH:29]([Cl:31])[Cl:30]>>[Cl:25][Si:24]([Cl:27])([Cl:26])[CH2:23][Si:29]([Cl:31])([Cl:30])[Cl:28]

参加物

4

反応物 3

HCID 15258Trichloro(chloromethyl)silaneHCID 24811TrichlorosilaneHCID 200231Benzyltributylphosphonium chloride

生成物 1

HCID 2756737Bis(trichlorosilyl)methane収率 68%

実験手順

In the same apparatus and procedure as Example 1 above, 0.22 g (0.67 mmol) of benzyltributylphosphonium chloride, 1.23 g (6.69 mmol) of (chloromethyl)trichlorosilane, and 2.71 g (20.0 mmol) of trichlorosilane were reacted at 160° C. for 15 hrs. The resulting mixture was distilled to give 1.13 g of 1,1,1,3,3,3-hexachloro-1,3-disilapropane (yield; 68%).

後処理

  1. distillationThe resulting mixture was distilled

出典と根拠

ORDレコード
ord-02059802c52946f29da4856f0cad71a8
出典データセット
uspto-grants-2002_05
特許番号
US06392077B1

反応ノート

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