化工社化工社 化学情報印刷レポート · 研究参考用
Methyldichlorosilane → Monophenethyldichlorosilane
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Methyldichlorosilane | HCID 6376 | — |
| 反応物 | Benzyl Chloride | HCID 7503 | — |
| 反応物 | Benzyltributylphosphonium chloride | HCID 200231 | — |
| 生成物 | Monophenethyldichlorosilane | HCID 123907249 | 240.6% |
反応手順
In the same apparatus and procedure as Example 1 above, 0.26 g (0.79 mmol) of benyltributylphosphonium chloride, 1.00 g (7.90 mmol) of benzyl chloride, and 2.73 g (23.7 mmol) of methyldichlorosilane were reacted at 200° C. for 2 hrs. The resulting mixture was distilled to give 0.39 g of benzylmethyldichlorosilane (yield; 24%).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US06392077B1 |
| 出典データセット | uspto-grants-2002_05 |
| ORD ID | ord-84c2b1619e68493395844cfc4bd26695 |
| 出典メモ | uspto-grants-2002_05 |