化工社化工社 化学情報印刷レポート · 研究参考用
Benzyl Chloride → Benzene, [(trichlorosilyl)methyl]-
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Benzyl Chloride | HCID 7503 | — |
| 反応物 | Dichlorosilane | HCID 61330 | — |
| 反応物 | Benzyltributylphosphonium chloride | HCID 200231 | — |
| 生成物 | Benzene, [(trichlorosilyl)methyl]- | HCID 69863 | 53% |
| 生成物 | Benzyldichlorosilane | HCID 101943102 | 19% |
反応手順
In the same apparatus and procedure as Example 1 above, 0.26 g (0.79 mmol) of benyltributylphosphonium chloride, 1.01 ml (7.98 mmol) of benzyl chloride, and 2.42 g (24.0 mmol) of dichlorosilane were reacted at 150° C. for 2 hrs. The resulting mixture was distilled to give 0.29 g of benzyldichlorosilane (yield; 19%) and 0.95 g of benzyltrichlorosilane (yield; 53%).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US06392077B1 |
| 出典データセット | uspto-grants-2002_05 |
| ORD ID | ord-380bfbcecc3d4ac1a46bb07f1b202964 |
| 出典メモ | uspto-grants-2002_05 |