化工社化工社 化学情報印刷レポート · 研究参考用
1,2-Dichloroethane → 1,1,1,4,4,4-Hexachloro-1,4-disilabutane
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 1,2-Dichloroethane | HCID 11 | — |
| 反応物 | Trichlorosilane | HCID 24811 | — |
| 触媒 | Tetrabutylphosphonium chloride | HCID 75311 | — |
| 生成物 | 1,1,1,4,4,4-Hexachloro-1,4-disilabutane | HCID 75631 | 54% |
反応手順
In the same apparatus and procedure as Example 1 above, 0.44 g (1.50 mmol) of tetrabutylphosphonium chloride, 0.74 g (7.5 mmol) of 1,2-dichloroethane, and 10.16 g (75.0 mmol) of trichlorosilane were reacted at 150° C. for 10 hrs. The resulting mixture was distilled to give 1.09 g of 1,2-bis(trichlorosilyl)ethane (yield; 54%).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US06392077B1 |
| 出典データセット | uspto-grants-2002_05 |
| ORD ID | ord-3a676ac9546048e5bab7a6b305272eae |
| 出典メモ | uspto-grants-2002_05 |