1,3-Dichloropropane → 1,3-BIS(TRICHLOROSILYL)PROPANE

HRID 1937093

反応式

HRID 1937093 の反応式
[Cl:1][CH2:2][CH2:3][CH2:4]Cl.[Cl:6][SiH:7]([Cl:9])[Cl:8]>[Cl-].C([P+](CCCC)(CCCC)CCCC)CCC>[Cl:6][Si:7]([Cl:9])([Cl:8])[CH2:2][CH2:3][CH2:4][Si:7]([Cl:9])([Cl:8])[Cl:6].[Cl:1][CH2:2][CH2:3][CH2:4][Si:7]([Cl:9])([Cl:8])[Cl:6]

参加物

5

反応物 2

HCID 88811,3-DichloropropaneHCID 24811Trichlorosilane

生成物 2

HCID 75693Trichloro(3-chloropropyl)silane収率 14%HCID 112438561,3-BIS(TRICHLOROSILYL)PROPANE収率 72%

試薬・触媒・溶媒 1

HCID 75311Tetrabutylphosphonium chloride触媒

実験手順

In the same apparatus and procedure as Example 1 above, 0.44 g (1.50 mmol) of tetrabutylphosphonium chloride, 0.85 g (7.5 mmol) of 1,3-dichloropropane, and 10.16 g (75.0 mmol) of trichlorosilane were reacted at 150° C. for 10 hrs. The resulting mixture was distilled to give 1.68 g of 1,3-bis(trichlorosilyl)propane (yield; 72%) and 0.22 g of (3-chloropropyl)trichlorosilane (yield; 14%).

後処理

  1. distillationThe resulting mixture was distilled

出典と根拠

ORDレコード
ord-4e600918000f4c37a1bb05bb1f3d518f
出典データセット
uspto-grants-2002_05
特許番号
US06392077B1

関連ノート

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