Oxygen → 1-Carboxy-3-nitro-5-adamantanol
反応式
[O:1]=O.[C:3]([C:6]12[CH2:15][CH:10]3[CH2:11][CH:12]([CH2:14][C:8]([N+:16]([O-:18])=[O:17])([CH2:9]3)[CH2:7]1)[CH2:13]2)([OH:5])=[O:4]>C(O)(=O)C>[C:3]([C:6]12[CH2:15][C:10]3([OH:1])[CH2:11][CH:12]([CH2:14][C:8]([N+:16]([O-:18])=[O:17])([CH2:9]3)[CH2:7]1)[CH2:13]2)([OH:5])=[O:4]参加物
4
実験手順
In an atmosphere of oxygen, the mixture of 10 mmole of 1-carboxy-3-nitroadamantane, 1 mmole of NHPI, 0.05 mmole of V(AA) 3 and 25 mL of acetic acid was allowed to react for 4 hours at 85° C. The reaction products were analyzed by gas-mass spectroscopy, and as a result, 1-carboxy-3-nitro-5-adamantanol was formed in a 80% yield.
後処理
- customto react for 4 hours at 85° C
出典と根拠
- ORDレコード
- ord-32be10716b084944abeb66e5d07af09e
- 出典データセット
- uspto-grants-2002_05
- 特許番号
- US06392104B1
反応ノート
読み込み中…