Benzoyl chloride → 4-(6-(Benzoyloxy)benzo[b]thiophen-2-yl)phenyl benzoate

反応式

[OH:1][C:2]1[CH:7]=[CH:6][C:5]([C:8]2[S:12][C:11]3[CH:13]=[C:14]([OH:17])[CH:15]=[CH:16][C:10]=3[CH:9]=2)=[CH:4][CH:3]=1.[C:18](Cl)(=[O:25])[C:19]1[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=1>>[C:18]([O:1][C:2]1[CH:7]=[CH:6][C:5]([C:8]2[S:12][C:11]3[CH:13]=[C:14]([O:17][C:18](=[O:25])[C:19]4[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=4)[CH:15]=[CH:16][C:10]=3[CH:9]=2)=[CH:4][CH:3]=1)(=[O:25])[C:19]1[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=1

参加物

反応物 2

HCID 7412Benzoyl chloride

HCID 4459202-(4-Hydroxyphenyl)benzo(b)thiophen-6-ol

生成物 1

HCID 99116044-(6-(Benzoyloxy)benzo[b]thiophen-2-yl)phenyl benzoate

実験手順

2-(4-Hydroxyphenyl)-6-hydroxybenzo[b]thiophene and benzoyl chloride were converted to the title compound by the procedure of Example 3 to yield a white crystalline solid. mp 216° C.-218° C.

出典と根拠

ORDレコード: ord-58c2985e105249dfb0e1e9482cecffde
出典データセット: uspto-grants-2002_05
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US06395769B1

反応ノート

読み込み中…